Gibson, Quinn DWen, DongshengLin, HaiZanella, MarcoDaniels, Luke MRobertson, Craig MClaridge, John BAlaria, JonathanDyer, Matthew SRosseinsky, Matthew J2024-03-132024-03-132024-06-03Gibson, Q D, Wen, D, Lin, H, Zanella, M, Daniels, L M, Robertson, C M, Claridge, J B, Alaria, J, Dyer, M S & Rosseinsky, M J 2024, 'Control of Polarity in Kagome-NiAs Bismuthides', Angewandte Chemie International Edition, vol. 63, no. 23, e202403670. https://doi.org/10.1002/anie.2024036701433-7851ORCID: /0000-0001-7020-199X/work/159510690https://hdl.handle.net/2164/23000Supplementary files include crystallographic information files for each of the five structures. The Supporting Information file contains details of the crystal structures of the five new materials reported here, energy dispersive X-ray spectroscopy data, DFT calculations, magnetization data, electronic transport data, and heat capacity data measured from the compounds reported here. Deposition Numbers https://www.ccdc.cam.ac.uk/services/structures?id=doi:10.1002/anie.202403670 2298182 (for Ni0.6Pt0.4Bi), 2298183 (for Ni0.7Pd0.2Bi), 2298184 (for Mn0.99Pd0.01Bi), 2298185 (for Ni0.9Bi), 2298186 (for Ni0.79Pd0.08Bi) contain the supplementary crystallographic data for this paper. These data are provided free of charge by the joint Cambridge Crystallographic Data Centre and Fachinformationszentrum Karlsruhe http://www.ccdc.cam.ac.uk/structures Access Structures service. Underlying data collected as part of this work is available at the University of Liverpool data repository at https://datacat.liverpool.ac.uk/id/eprint/2470.898197647717677engSubstantive connection via eligible employment contractKagomeNiAsintermetallicsPolar metalQD ChemistryEngineering and Physical Sciences Research Council (EPSRC)EP/V026887Supplementary Informationhttps://onlinelibrary.wiley.com/action/downloadSupplement?doi=10.1002%2Fanie.202403670&file=anie202403670-sup-0001-misc_information.pdfhttps://onlinelibrary.wiley.com/action/downloadSupplement?doi=10.1002%2Fanie.202403670&file=anie202403670-sup-0001-Mn099Pd001Bi.cifhttps://onlinelibrary.wiley.com/action/downloadSupplement?doi=10.1002%2Fanie.202403670&file=anie202403670-sup-0001-Ni06Pt04Bi.cifhttps://onlinelibrary.wiley.com/action/downloadSupplement?doi=10.1002%2Fanie.202403670&file=anie202403670-sup-0001-Ni079Pd008Bi.cifhttps://onlinelibrary.wiley.com/action/downloadSupplement?doi=10.1002%2Fanie.202403670&file=anie202403670-sup-0001-Ni07Pd02Bi.cifhttps://onlinelibrary.wiley.com/action/downloadSupplement?doi=10.1002%2Fanie.202403670&file=anie202403670-sup-0001-Ni09Bi.cifQDJournal article10.1002/anie.2024036706323